The Mechanism of Dioxygen Reduction at Iron meso-Tetrakis (Pyridyl) Porphyrin: a Spectroelectrochemical Study
1998 ◽
Vol 02
(03)
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pp. 249-260
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Keyword(s):
The mechanism of the dioxygen interaction with and reduction reaction at iron α,β,γ,δ-tetra(4-pyridyl) porphyrin ( FeTPyP ) deposited on carbon and silver supporting electrodes was investigated with cyclic voltammetry and FTIR, UV-vis and resonance Raman spectroscopies. Results indicate a strong influence of the ligand upon the reduction electrocatalysis. Spectroelectrochemical results support a two-electron pathway resulting most probably in hydrogen peroxide as the primary reduction product.
1999 ◽
Vol 03
(04)
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pp. 265-282
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2006 ◽
Vol 258-260
◽
pp. 327-332
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2009 ◽
Vol 610-613
◽
pp. 161-164
2020 ◽
Vol 13
(1)
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pp. 238-245
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2019 ◽
Vol 11
(38)
◽
pp. 35410-35419
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